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Buenos días<br>
Vamos a dar comienzo al ciclo de de Seminarios INA previsto
programado para los meses de marzo a junio.<br>
Adjunto envío cartel anunciador del primer seminario del ciclo.<br>
<br>
Manipulation of oxygen vacancies by local electric fields in 3d
oxides<br>
Francisco Rivadulla<br>
Jueves, 11 de abril, 12:00 h. Aula Edificio i+D<br>
<br>
<p class="MsoNormal" style="text-align:justify"><span
style="font-size:10.0pt;line-height:115%;font-family:"Arial","sans-serif";color:#333333;background:white;mso-ansi-language:EN-US"
lang="EN-US">Oxygen vacancies play a
central role in the physics and chemistry of</span><span
style="font-size:10.0pt;line-height:115%;font-family:"Arial","sans-serif";color:#333333;mso-ansi-language:EN-US"
lang="EN-US"> <span style="background:white">transition
metal oxides. For the case of 3d-oxoperovskites, the</span>
<span style="background:white">possibility of the metal to
adopt different valence
states, together</span> <span style="background:white">with
the stability of
the structure in the presence of a large number</span> <span
style="background:
white">of vacancies in the anion sublattice, offers a vast
range of</span> <span style="background:white">possibilities
to control the magnetic, optical and
transport</span> <span style="background:white">properties
of these materials.
However, achieving a precise control</span> <span
style="background:white">over
the amount of vacancies and their spatial distribution is
still</span> <span style="background:white">far from
possible.</span></span></p>
<p class="MsoNormal" style="text-align:justify"><span
style="font-size:10.0pt;line-height:115%;font-family:"Arial","sans-serif";color:#333333;background:white;mso-ansi-language:EN-US"
lang="EN-US">In the first part of
this talk I will discuss the effect of epitaxial</span><span
style="font-size:10.0pt;line-height:115%;font-family:"Arial","sans-serif";color:#333333;mso-ansi-language:EN-US"
lang="EN-US"> <span style="background:white">strain
on the enthalpy of formation of oxygen vacancies in thin
films</span> <span style="background:white">of SrTiO3. I
will describe the possibility of using
the local electric</span> <span style="background:white">field
generated by an
AFM-tip to create accumulation/depletion regions</span> <span
style="background:
white">of oxygen vacancies in SrTiO3 with sub-micron
resolution. Relaxation</span>
<span style="background:white">experiments were used to obtain
the room temperature
diffusion</span> <span style="background:white">coefficient
of the vacancies,
under different degrees of epitaxial</span> <span
style="background:white">strain.</span></span></p>
<p class="MsoNormal" style="text-align:justify"><span
style="font-size:10.0pt;line-height:115%;font-family:"Arial","sans-serif";color:#333333;background:white;mso-ansi-language:EN-US"
lang="EN-US">In the second part of
the talk I will discuss how in some cases the</span><span
style="font-size:10.0pt;line-height:115%;font-family:"Arial","sans-serif";color:#333333;mso-ansi-language:EN-US"
lang="EN-US"> <span style="background:white">electric
field generated by the AFM-tip can be used to induce a local</span>
<span style="background:white">crystallographic transition
between two states with
different</span> <span style="background:white">functionalities.
In this case,
oxygen vacancies accumulated by the</span> <span
style="background:white">electric
field reorganize spontaneously to form a different crystal</span>
<span style="background:white">structure through a topotactic
transformation,
defining a new</span> <span style="background:white">functional
state with
extra stability against diffusion. I will</span> <span
style="background:white">discuss
the cases of SrFeO3-d and LaSrMnO3-d. </span></span><span
style="mso-ansi-language:EN-US" lang="EN-US"></span></p>
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<br>
Saludos<br>
Raúl<br>
<br>
<pre class="moz-signature">--
Raúl Mendoza Jiménez
Técnico de Apoyo a la Investigación INA
c/Mariano Esquillor s/n. (50018) zaragoza.
edificio i+d+i. Campus Rio Ebro. Universidad de Zaragoza
INA - Instituto de Nanociencia de Aragón
tel: +34 976 762865. fax: +34 976 762776
web: <a class="moz-txt-link-freetext" href="http://ina.unizar.es">http://ina.unizar.es</a>
e-mail: <a class="moz-txt-link-abbreviated" href="mailto:rmendoza@unizar.es">rmendoza@unizar.es</a>
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